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Worldwide Thin-film Photovoltaics

Current Status and R&D


Published by MRG, Inc. and Fuji-Keizai
February 2009, 152 pages

Available in English or Japanese
Hard Copy Print Edition $1,495 USD
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Executive Summary

Conventional bulk silicon based PV cells have been used since the 1960s and have undergone substantial developments, however they are the most costly to manufacture especially in light of the current worldwide silicon shortage. These cells types accounted for more than 83 percent of the market share in 2007. Thin-film PV cells have been evolving since the early 1970s, and organics PV cells since the 1990s and accounted for about 17 percent of the total PV market in 2007, making it one of the fast growing technologies in the whole of the alternative energy sector. These cells are made by directly depositing photoactive material onto a thin substrate, and are therefore much thinner and require less material than conventional PV cells and offer increasing efficiencies. There are several important thin-film PV cell types: amorphous silicon (a-Si); cadmium telluride (CdTe); and copper indium diselenide/copper indium gallium diselenide (CIS / CIGS), and also organic systems. In 2007, NREL demonstrated CIGS PV cells with 19.9 percent efficiency, which is still very far from that reported by University of Delaware researchers for crystalline silicon (42.8 percent), but nonetheless demonstrates the tremendous potential for thin-film PV and its great applicability in many applications.

Key drivers enabling the development and use of organic and thin-film PV cells include government programs, silicon costs and availability.

The current main thin-film PV technologies accounted for about 17 percent of the total PV market in 2007, and this is expected to increase to more than 32 percent (about 4 GW) by 2013. A number of activities being carried out by organizations in the PV sector are helping the development of this emerging market.

The prospects for organic-based PV devices are continuing to improve as development gets closer to commercialization, and an efficiency of 8-10 percent is likely in the foreseeable future. The success of organic and thin-film PVs will depend on their ability to be cost-competitive when compared with existing electrical sources such as rigid PVs and batteries, and with emerging technologies such as fuel cells.

Thin-film PV cells based on crystalline and amorphous silicon, CdTe, and CIGS are in various phases of manufacture, and it is expected that they will achieve the cost reductions needed to compete directly with the other forms of energy. These reductions will become more significant when thin-film technologies are produced directly on building materials such as tiles and bricks.

PV applications can be roughly divided into three categories, those involving: power generation installations, conventional electronics and disposable electronics.

For the large-scale applications of PV in both building installed PV, rural electrification and irrigation pumps projects PV manufacturing costs must be reduced by at least a factor of two. As production costs decline, demand for PV electricity will outstrip system supply.

Leading PV developers along the supply chain have indicated that in both the US and global PV markets that for the last quarter of 2008 and through at least the first half of 2009, there will be softer conditions, which will prevent the rapid growth expected before the credit crunch, and this may even flow over into 2010. This is not due to any lack of technological innovations discussed in this report, but rather stems from a concern over reduced funding and spending levels on solar projects and the effect of the falling oil price – which in turn will make customers think twice about spending their savings on solar energy. That say and done, during in 2009, revenues may pick up due to strong demand for PV. Also, consolidation of the industry during 2009 within the industry will help offset these concerns, and even lead to some reduction in PV module prices. Table E-4 (not display it here) summarizes the latest outlook for the worldwide thin-film PV market by thin-film segment over the next 5 years. The report includes trends broken down by volume and material types.

 

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Table of Contents


  Executive Summary
   
1 Introduction and Methodology
1.1 Introduction
1.2 Scope
1.3 Methodology
   
2 PV Technology and Developer Overview
2.1

Cell Principles and Operation

2.1.1 Heterojunction Cells
2.1.2 Ordered Heterojunctions
2.1.3 Multijunctions
2.2 Evolution of Thin-film PV
2.2.1 Evolution of Organic and DSC PV Cells
2.2.2 Evolution of Silicon Thin-film PV Cells
   
3 Thin-film PV Materials and Properties: Developer's Positioning
3.1 The growing Interest in Thin-film PVs
3.2 Thin-film Silicon
3.2.1 Amorphous Silicon
3.2.2 Nanocrystalline Silicon
3.2.3 Protocrystalline Silicon 
3.2.4 Monocrystalline Silicon
3.3 Cadmium Telluride Thin-films (CdTe)
3.4 Chalcopyrite Thin-film Compounds (CIS, CIGS)
3.5 Dye-sensitized Thin-film Cells
3.5.1 Cells
3.5.2 Dye Sensitizer Materials
3.5.3 Electrolytes
3.6 Organic PV (OPV) Cells
3.6.1 Cells
3.6.2 OPV Materials
3.6.2.1 Conducting Polymers
3.6.2.2 Semiconducting Materials
3.6.2.3 Transparent Conducting Materials
3.7 Nanomaterials
3.7.1 Carbon Nanotubes
3.7.2 Quantum Dots
3.8 Flexible Substrates
   
4 Manufacturing Overview
4.1 Main Processes for Producing Thin-film PV Cells
4.1.1 Gravure Printing
4.1.2 Inkjet Printing
4.1.3 Screen Printing
4.1.4 Other Printing Methods
4.2 Film/device Quality and Substrate Compatibility
4.3 Economics
4.4 Vacuum Deposition
4.4.1 CIGS Manufacture
4.4.2 CdTe PV Cell Manufacture
4.5 Roll-to-Roll
4.5.1 Konarka
4.5.2 G24 Innovations
4.5.3 Nanosolar
4.5.4 Other Developments
4.6 Thin-film on Glass
3.6.2 Thin-film on Flex
   
5 Commercial Applications
5.1 Building-integrated Power Generation
5.2 Consumer Electronics
5.3 Military
5.4 Packaging
5.5 Solar Chargers
5.6 Smart Fabrics
5.7 Space Applications
   
6 Worldwide Market Outlook
6.1 Recent activities
6.2 Silicon costs
6.3

Current Status and Future Outlook for Thin-film PV Cells – Global Trends for 2007-2013

   
7 Ongoing R&D and Development Trends by Product Segment
7.1 Technologies Under Development
7.1.1 Spheral Crystalline Silicon
7.1.2 Organic PV Cells
7.1.3 Dye Sensitized Cells
7.1.4 Third-generation PV Cells
7.2 Potential Improvements in Conversion Efficiencies
7.2.1 Blends of Electron and Hole Transporting Polymers
7.2.2 High-band-gap Semiconducting Oxides
7.2.3 Luminescent Concentrators
7.2.4 Ionic Solid Electrolyte
7.2.5 Micro-morph
7.2.6 Stability of Organic Materials
7.3 Materials Capable of Absorbing a Wider Range of Light Wavelengths
7.4 New Materials
7.4.1 Hybrid Organic/Inorganic Semiconductors
7.4.2 Nanowires
7.5 Challenges for Further Development
   
8 Key Findings in this Report
8.1 Introduction
8.2 Evolution and Development for Thin-film PV Cells
8.2.1 Thin-film Silicon
8.2.2 Cadmium Telluride (CdTe)
8.2.3 CIGS and CIS Thin-films
8.2.4 DSCs
8.2.5 OPV
8.3 Manufacturing
8.3.1

Processes for Producing Thin-film PV Cells

8.3.2 CIGS Manufacture
8.3.3 CdTe PV Cell Manufacture
8.3.4 Roll-to-roll Processing
8.4 Commercial Applications
8.4.1 BIPV
8.4.2 Consumer Electronics
8.4.3 Military
8.4.4 Packaging
8.4.5 Solar Chargers
8.4.6 Smart Fabrics
8.4.7 Space Applications
8.5 Market Outlook
   
9 Leading Photovoltaic Material and Cell Suppliers
9.1

Commercial Suppliers

Common Research Item
-Company HQ Location
-URL
-Production Facility Location
-Founded
-# Employees
-Revenue or Financial Status (depending if public or private company)
-Production Capacity (monthly or yearly)
-Applications Focus
-Technology/Product Developed or R&D
-Commercialization
-Strategic Alliance

9.1.1-9.1.48 (Total 48 Companies)
9.2

Research Organizations

Common Research Item
-Location
-URL
-Description of Technology Innovation
-Research Target & Trends
-Application Targeted
-Strategic Alliance

9.2.1-9.2.25 (Total 25 Research Organizations)
   
Appendix 1 - Methodology for Reporting Efficiencies

 

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Table of Figures

Figure 2-1: Main PV Cell Efficiencies (1993-2008)
Figure 3-1: Thin-Film PV Cell Efficiencies (1993-2008)
Figure 3-2: Structure and Operating Principle of a Dye-Sensitized PV Cell
Figure 3-3: PEDOT Nanofibers
Figure 4-1: Process Sequence for Manufacturing Thin-film Modules
Figure 4-2: Gravure Printing Process
Figure 4-3: Ink-jet Deposition Mechanisms
Figure 4-4: Screen Printing Process
Figure 4-5: Efficiency and Cost Projections for First (I), Second (II), and Third Generation(III) PV Technologies
Figure 6-1: PV Market Outlook by Production Capacity 2007-2013
Figure 6-2: Thin-film PV Production by Capacity (MWp)
Figure 6-3: Thin-film PV Production Capacity by Percentage
Figure 6-4: Thin-film PV Revenues by US$M
Figure 6-5: Thin-film PV Revenue by Percentage
Figure 6-6: Thin-film PV Revenue by Application ($ millions)
Figure 6-7: Thin-film PV Revenue by Application as a Percentage
Figure 8-1: Main PV Cell Efficiencies (1993-2008)

 

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Table of Tables

Table E-1: Comparison of Organic and Thin-film PV Cell Technologies
Table E-2: Activities in the PV Market During 2008
Table E-3: Best Fit Technology by Application
Table E-4: Summary of the Thin-film PV Market by Segment ($ millions)
Table 2-1: Developer’s Technology Positioning
Table 2-2: Technical Challenges Facing Organic PV Cell Development
Table 2-3: Comparison of Main PV Cell Technologies (2008)
Table 2-4: Technology Developments for PV Efficiencies
Table 2-5: Organic PV Cell Development
Table 2-6: Advantages of Organic PV Cells
Table 2-7: DSC Cell Development
Table 2-8: Thin-Film Silicon PV Cell Development
Table 3-1: Developer’s Positioning
Table 3-2: Developer’s Current Status
Table 3-3: Amorphous Silicon Thin-film PV Cell Data
Table 3-4: Amorphous Silicon – Developments
Table 3-5: Physical Properties of CdTe Thin-film PV
Table 3-6: Thin-film CdTe PV Technology Developments
Table 3-7: CIGS PV Technology Advantages
Table 3-8: CIGS Cell Efficiency Developments by Substrate
Table 3-9: Advantages of Dye-Sensitized Cells
Table 3-10: DSC PV Technology Developments
Table 3-11: DSC - Today's Cost Breakdown
Table 3-12: Comparison of DSC Sensitizers
Table 3-13: Polymer Conductive Coatings – Commercially Available and In-Development
Table 3-14: Mobilities for Some Common P-Channel Organic Semiconductors
Table 3-15: Mobilities of Common N-Channel Organic Semiconductors
Table 3-16: Transparent Conducting Oxides
Table 3-17: Carbon Nanotubes For Thin-film PV Cells
Table 3-18: Vitex Flexible Glass Substrate
Table 4-1: Developer/Supplier’s Positioning
Table 4-2: Comparison of Common Printing Processes
Table 4-3: Thin-film CIGS PV Technology
Table 4-4: CdTe Thin-film PV Cell Properties
Table 4-5: Manufacturing Processes Used for CIGS PV Cells
Table 4-6: Thin-film PV Cell Developments
Table 5-1: Best Fit PV Technology by Application
Table 5-2: Selected Commercial BIPV Systems – by PV Technology
Table 6-1: Activities in the PV Market During 2008
Table 6-2: Principal Polysilicon Suppliers (2006)
Table 6-3: PV Market Outlook by Production Capacity 2007-2013
Table 6-4: Thin-film PV Production by Capacity (MWp)
Table 6-5: Thin-film PV Production Capacity by Percentage
Table 6-6: Thin-Film PV Revenues by US$M
Table 6-7: Thin-film PV Revenue by Percentage
Table 6-8: Thin-film PV Revenue by Application ($ millions)
Table 6-9: Thin-film PV Revenue by Application as a Percentage
Table 7-1: Thin-film PV Future Trends
Table 7-2: Cu2S/CdS Nanocrystal and Thin-film Comparison
Table 8-1: Comparison of Thin-film and Organic PV Cell Technologies (2008)
Table 8-2: Thin-film Silicon PV Developments
Table 8-3: Amorphous Silicon PV – Developments
Table 8-4: Thin-film PV CdTe Developments
Table 8-5: Thin-film CIGS PV Cell Developments
Table 8-6: DSC PV Developments
Table 8-7: Organic PV Developments
Table 8-8: Transparent Conducting Material Developments
Table 8-9: Carbon Nanotubes for Thin-film PV Cells
Table 8-10: Comparison of Conventional Printing Processes
Table 8-11: CIGS Thin-film PV Technology
Table 8-12: CdTe Thin film PV Cell Properties
Table 8-13: Manufacturing Processes Used for PV cells
Table 8-14: Best Fit Technology by Application
Table 9-1: Material Suppliers – by Material Type
Table 9-2: Amorphous Silicon Thin-Film PV Cell Suppliers
Table 9-3: CdTe Thin-film PV Cell Suppliers
Table 9-4: CIGS Thin-film PV Cell Suppliers
Table 9-5: Dye Sensitized PV Cell Suppliers
Table 9-6: OPV Material and Cell Developers

 

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Worldwide Thin-film Photovoltaics - Current Status and R&D (February 2009) is 152 pages and is available in a printed English language edition for $1,495.00 USD, a PDF single-departmental license for $2,295.00 USD, and a coporate-wide license for $3,495.00 USD. For more information or to order the report, contact Rob Smith at 1-408-453-5553 or rsmith@mrgco.com.

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